Inorganic perchlorato complexes
Identifieur interne : 000343 ( France/Analysis ); précédent : 000342; suivant : 000344Inorganic perchlorato complexes
Auteurs : Jean-Louis Pascal [France] ; Frédéric Favier [France]Source :
- Coordination Chemistry Reviews [ 0010-8545 ] ; 1998.
Abstract
A summary is given of the synthesis of non-solvated inorganic perchlorato complexes and their structural characterization. The synthesis of perchlorato complexes has been extended to many elements of the periodic table by the use of efficient perchlorating reagents such as perchloric acid, HClO4–Cl2O7 oleums and chlorine trioxide, Cl2O6. X-ray diffraction, EXAFS and vibrational spectroscopy show that the perchlorato ligand, [ClO4], can be strongly bonded to metals in various bonding arrangements: monodentate, bridging or chelating bidentate, simply bridging or simultaneously bridging and chelating tridentate. It is mostly an assembling ligand.
Url:
DOI: 10.1016/S0010-8545(98)00102-7
Affiliations:
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ISTEX:457EC78732F4BD495FE013260C2F36BE5DE6BF7FLe document en format XML
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Bataillon, 34095 Montpellier Cedex 5</wicri:regionArea><placeName><region type="region" nuts="2">Occitanie (région administrative)</region><region type="old region" nuts="2">Languedoc-Roussillon</region><settlement type="city">Montpellier</settlement></placeName><orgName type="university">Université Montpellier 2</orgName></affiliation></author></analytic><monogr></monogr><series><title level="j">Coordination Chemistry Reviews</title><title level="j" type="abbrev">CCR</title><idno type="ISSN">0010-8545</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1998">1998</date><biblScope unit="volume">178–180</biblScope><biblScope unit="supplement">P1</biblScope><biblScope unit="page" from="865">865</biblScope><biblScope unit="page" to="902">902</biblScope></imprint><idno type="ISSN">0010-8545</idno></series><idno type="istex">457EC78732F4BD495FE013260C2F36BE5DE6BF7F</idno><idno type="DOI">10.1016/S0010-8545(98)00102-7</idno><idno type="PII">S0010-8545(98)00102-7</idno></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">0010-8545</idno></seriesStmt></fileDesc><profileDesc><textClass></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">A summary is given of the synthesis of non-solvated inorganic perchlorato complexes and their structural characterization. The synthesis of perchlorato complexes has been extended to many elements of the periodic table by the use of efficient perchlorating reagents such as perchloric acid, HClO4–Cl2O7 oleums and chlorine trioxide, Cl2O6. X-ray diffraction, EXAFS and vibrational spectroscopy show that the perchlorato ligand, [ClO4], can be strongly bonded to metals in various bonding arrangements: monodentate, bridging or chelating bidentate, simply bridging or simultaneously bridging and chelating tridentate. It is mostly an assembling ligand.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Languedoc-Roussillon</li><li>Occitanie (région administrative)</li></region><settlement><li>Montpellier</li></settlement><orgName><li>Université Montpellier 2</li></orgName></list><tree><country name="France"><region name="Occitanie (région administrative)"><name sortKey="Pascal, Jean Louis" sort="Pascal, Jean Louis" uniqKey="Pascal J" first="Jean-Louis" last="Pascal">Jean-Louis Pascal</name></region><name sortKey="Favier, Frederic" sort="Favier, Frederic" uniqKey="Favier F" first="Frédéric" last="Favier">Frédéric Favier</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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